Hmmmm, make sure you test at the same time of day each time, I have seen similar if I test first thing in the morning. I believe (read on internet, not sure how reliable te sourceS?) that PH fluctuates through the day and night. I got silly readings the first time I did a test in the morning, but when I tested again lunch time (usual time) it was back to normal? I know this goes against everything you are told with shrimp keeping, but if it is 'natural' and probably happening in all tanks (?) then it's probably not a problem, it never affected my shrimp or fish! You could try the same test with the other tank and see if the same happens just to give you peace of mind? IF you did the test the same time of day as previously then let me know and we can have a rethink?
On the plus side though at least both tests are in line with each other so they are probably both right/accurate!
Don't worry about the PH reading, just make sure you set a regular time like I did for doing the tests, but avoid too early in the day. I can't comment on the film on the water but if it bothers you you could get a skimmer?
Most important though, have the shrimp stopped dying?
Simon