It's unfortunate that RO water or even rain water is not an option.
Cause the most obvious (and immediate) action to take is to reduce that TDS level down to around 150.
If your only option is to use tap water, then please run some tests of the tap water for us - pH, and TDS. Without any added pH Down or water conditioner.
Since your TDS is so high already, my recommendation is to forgo adding fluval shrimp minerals (which raises TDS). Drip in the change water slowly over several hours. You can go faster than 8.5L over 10 hours. 8.5L in a 100L tank is nothing - 1 hour is sufficient. I'd be changing 20L of water at a time. Drip new aged water in over 5 hours. That should be much faster water changes.
The other issue seems to be pH, or rather the instability of the pH reading. It's rising. you're countering it with pH down chems. It rises again as the chems wear off. You need to find the cause of the pH rise. Could possibly be the pH of the water out of your tap is already high. Or something in your tank is buffering it higher - rocks, cheap ceramic ring filter media, old carbon media are some possibilities. You can test them in some clean water out of the tank/filter. Check pH before adding the suspect item. Then test again after 24 hours.
Also, how old is the tank since it was setup?
I truly believe (not physically tested yet) that most tanks will run low on Calcium and Magnesium after 3 months. Even if you add a little back in each water change using Salty Shrimp or whatever re-mineralising water treatment. More Ca and Mg needs to be added or it will be depleted in that time frame causing moulting issues. If Calcium : Magnesium is low, take up Newbreeds offer immediately. If you need more Ca and Mg, our sponsors Aquotix AOS sells it fairly cheap for the amount you get.
Next time it rains, put lots of buckets out.
But if your aged tap water has these readings "TDS 31, ph 6.7, ammonia 0, gh 0, kh 0", then you have very good tap water for fish/shrimp. But I doubt tap water pH is that low out of the tap. Is this 6.7pH with pH down?
Hope that helps, you now have a few ideas to act on immediately.